12 research outputs found

    Solid-liquid interfacial energy of camphene

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    The Gibbs-Thomson coefficient and the solid-liquid interfacial energy for camphene have been measured to be (8.58 ± 0.96) × 10-8 K m and (4.43 ± 0.49) × 10-3 J m-2, respectively, by a direct method. The grain boundary energy of camphene has also been calculated to be (8.36 ± 0.92) × 10-3 J m-2 from the observed grain boundary groove shapes. © 1999 Elsevier Science S.A. All rights reserved.The authors would like to thank Erciyes University Research Foundation for financial support to the project

    Directional solidification of pure succinonitrile and succinonitrile- salol alloys

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    Pure succinonitrile (SCN) and succinonitrile-salol alloys with four different concentrations of salol were unidirectionally solidified at five different growth rates in a temperature gradient. The microstructure parameters, viz., the primary dendrite arm spacing ?1, dendrite tip radius R and mushy zone depth d, were measured. The dependence of the microstructure parameters on the solidification parameters for pure SCN and SCN-Salol alloys were determined via linear regression analysis. The results are compared with published data

    Experimental determination of solid-liquid interfacial energy for Zn solid solution in equilibrium with the Zn-Al eutectic liquid

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    The equilibrated grain boundary groove shapes for the Zn solid solution in equilibrium with the Zn-Al eutectic liquid were observed by rapid quenching. From the observed grain boundary groove shapes, the Gibbs-Thomson coefficient and the solid-liquid interfacial energy for the Zn solid solution in equilibrium with the Zn-Al eutectic liquid have been determined to be (5.80 +/- 0.18) X 10(-8) Km and (93.496 +/- 7.57) X 10(-3) Jm(-2) with the numerical method and from the Gibbs-Thomson equation, respectively. The grain boundary energy for the same material has been calculated to be (182.302 +/- 18.23) X 10(-3) Jm(-2) from the observed grain boundary groove shapes. The thermal conductivities of the solid and liquid phases for Zn-5 wt pct Al and Zn-0.5 wt pct Al alloys have also been measured

    Measurement of Solid-Liquid Interfacial Energy for Solid Zn in Equilibrium with the ZnMg Eutectic Liquid

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    The equilibrated grain boundary groove shapes for solid Zn in equilibrium with the ZnMg eutectic liquid were observed on rapidly quenched samples. The Gibbs-Thomson coefficient for the solid Zn has been determined to be (10.64 +/- 0.43) x 10(-8) K m from the observed grain boundary groove shapes with the present numerical model, and the solid-liquid interfacial energy for the solid Zn in equilibrium with the ZnMg eutectic liquid has been obtained to be (89.16 +/- 8.02) x 10(-3) J m(-2) from the Gibbs-Thomson equation. The grain boundary energy for the solid Zn has also been calculated to be (172.97 +/- 20.76) x 10(-3) J m(-2) from the observed grain boundary groove shapes
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